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Top quality factory supply 690-94-8 DIMETHYL(VINYL)ETHYNYLCARBINOL at low price
- Molecular Formula: C7H10 O
- Molecular Weight: 110.156
- Vapor Pressure: 0.858mmHg at 25°C
- Refractive Index: 1.4700 (estimate)
- Boiling Point: 159.9°C at 760 mmHg
- PKA: 12.94±0.29(Predicted)
- Flash Point: 59.9°C
- PSA： 20.23000
- Density: 0.917g/cm3
- LogP: 0.94670
DIMETHYL(VINYL)ETHYNYLCARBINOL(Cas 690-94-8) Usage
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General Description |
Dimethyl(vinyl)ethynylcarbinol is a chemical compound with the formula C6H10O. It is a colorless liquid with a distinct odor, and is used as a reagent in organic synthesis. Dimethyl(vinyl)ethynylcarbinol is commonly employed as an intermediate in the production of pharmaceuticals, agrochemicals, and other specialty chemicals. It is known for its ability to act as a nucleophile in various reactions, and is often utilized in the creation of complex organic molecules. Overall, dimethyl(vinyl)ethynylcarbinol is a versatile and important chemical in the field of organic chemistry. |
InChI:InChI=1/C7H10O/c1-4-5-6-7(2,3)8/h4,8H,1H2,2-3H3
690-94-8 Relevant articles
SUBSTITUTED IMIDAZOLECARBOXYLATE DERIVATIVES AND THE USE THEREOF
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Paragraph 0912-0914, (2020/12/08)
A compound is shown in formula (I). The ...
Diastereo- and enantioselective iridium-catalyzed carbonyl propargylation from the alcohol or aldehyde oxidation level: 1,3-enynes as allenylmetal equivalents
Geary, Laina M.,Woo, Sang Kook,Leung, Joyce C.,Krische, Michael J.
supporting information; experimental part, p. 2972 - 2976 (2012/04/18)
Axial to axial to point chirality transf...
Ruthenium-catalyzed reductive coupling of 1,3-enynes and aldehydes by transfer hydrogenation: Anti-diastereoselective carbonyl propargylation
Geary, Laina M.,Leung, Joyce C.,Krische, Michael J.
supporting information, p. 16823 - 16827 (2013/03/28)
Under the conditions of ruthenium-cataly...
Direct N- and C-vinylation with trimethoxyvinylsilane
Arsenyan, Pavel,Petrenko, Alla,Paegle, Edgars,Belyakov, Sergey
experimental part, p. 326 - 328 (2012/02/04)
Treatment of nucleobases, nucleosides, 5...
690-94-8 Process route
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593-60-2,25951-54-6
Vinyl bromide
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115-19-5
2-methyl-but-3-yn-2-ol
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-
5929-72-6
2,7-dimethyl-octa-3,5-diyne-2,7-diol
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-
690-94-8
dimethyl(vinylethynyl)carbinol
| Conditions | Yield |
|---|---|
|
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine;
In
tetrahydrofuran;
at 20 ℃;
Inert atmosphere;
|
20%
42% |
-
-
593-60-2,25951-54-6
Vinyl bromide
-
-
115-19-5
2-methyl-but-3-yn-2-ol
-
-
690-94-8
dimethyl(vinylethynyl)carbinol
| Conditions | Yield |
|---|---|
|
With
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran; diethylamine;
at 0 - 20 ℃;
for 12h;
|
91%
|
|
With
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); potassium hydroxide;
In
tetrahydrofuran; diethylamine;
at 0 - 20 ℃;
for 12h;
|
91%
|
|
With
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diethylamine;
In
tetrahydrofuran;
at 23 ℃;
for 2.5h;
|
84%
|
|
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran; diethylamine;
at 23 ℃;
for 2.5h;
|
84%
|
|
With
copper(l) iodide; diisopropylamine;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran;
at 20 ℃;
|
80%
|
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