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Cost-effective and customizable Ethyl 2-oxocyclopentanecarboxylate 611-10-9 for sale
- Molecular Formula: C8H12O3
- Molecular Weight: 156.181
- Appearance/Colour: clear colourless to pale yellow liquid
- Vapor Pressure: 0.0743mmHg at 25°C
- Refractive Index: n20/D 1.452(lit.)
- Boiling Point: 228.2 °C at 760 mmHg
- PKA: 12.02±0.20(Predicted)
- Flash Point: 77.8 °C
- PSA： 43.37000
- Density: 1.12 g/cm3
- LogP: 0.91870
Ethyl 2-oxocyclopentanecarboxylate(Cas 611-10-9) Usage
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Synthesis Reference(s) |
Journal of the American Chemical Society, 85, p. 207, 1963 DOI: 10.1021/ja00885a021The Journal of Organic Chemistry, 55, p. 5037, 1990 DOI: 10.1021/jo00304a014Tetrahedron Letters, 22, p. 1353, 1981 DOI: 10.1016/S0040-4039(01)90316-8 |
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Hazard |
Vapors are toxic, as is skin contact. |
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General Description |
Phase-transfer benzylation reaction of ethyl 2-oxocyclopentanecarboxylate with benzyl bromide in microreactor has been investigated. Ethyl 2-oxocyclopentanecarboxylate participates in cobalt (II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols. |
InChI:InChI=1/C8H12O3/c1-2-11-8(10)6-4-3-5-7(6)9/h6H,2-5H2,1H3/t6-/m1/s1
611-10-9 Relevant articles
Highly diastereoselective mercury-mediated synthesis of functionalized 2-azabicyclo[3.3.0]octane derivatives
Pe?anha, Emerson P,Verli, Hugo,Rodrigues, Carlos R,Barreiro, Eliezer J,Fraga, Carlos A.M
, p. 1607 - 1611 (2002)
In this paper we described the synthesis...
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Komppa,Talvitie
, p. 3,21 (1941)
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Studies toward the diastereoselective reduction of 2-alkoxycarbonyl-2-allyl-cyclopentanone derivatives with boron hydrides
Fraga,Barreiro
, p. 1133 - 1144 (1995)
The reduction of 2-alkoxycarbonyl-2-ally...
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Zupancic,Trpin
, p. 369 (1967)
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Coumarin-dithiocarbamate hybrids as novel multitarget AChE and MAO-B inhibitors against Alzheimer's disease: Design, synthesis and biological evaluation
He, Qi,Liu, Jing,Lan, Jin-Shuai,Ding, Jiaoli,Sun, Yongbing,Fang, Yuanying,Jiang, Neng,Yang, Zunhua,Sun, Liyuan,Jin, Yi,Xie, Sai-Sai
supporting information, p. 512 - 528 (2018/09/29)
A series of new coumarin-dithiocarbamate...
On the ozonolysis of unsaturated tosylhydrazones as a direct approach to diazocarbonyl compounds
Fegheh-Hassanpour, Younes,Ebrahim, Faisal,Arif, Tanzeel,Sintim, Herman O.,Claridge, Timothy D. W.,Amin, Nader T.,Hodgson, David M.
, p. 2876 - 2884 (2018/05/03)
The scope and limitations are described ...
1-(Arylmethyl)-5,6,7,8-tetrahydroquinazolline-2,4-diones and Analogs and the Use Thereof
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Paragraph 0151; 0199, (2014/09/30)
Disclosed are novel 1-(arylmethyl)-5,6,7...
Phosphate tricyclic coumarin analogs as steroid sulfatase inhibitors: Synthesis and biological activity
Kozak, Witold,Dasko, Mateusz,Maslyk, Maciej,Pieczykolan, Jerzy S.,Gielniewski, Bartlomiej,Rachon, Janusz,Demkowicz, Sebastian
, p. 44350 - 44358 (2014/12/10)
In the present work, we report convenien...
611-10-9 Process route
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64-17-5
ethanol
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53007-35-5
1,1,4-butanetricarboxylic acid triethyl ester
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141-52-6
sodium ethanolate
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51657-17-1
diethyl cyclopentanone-2,5-dicarboxylate
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611-10-9
2-ethoxycarbonyl-1-cyclopentanone
| Conditions | Yield |
|---|---|
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626-86-8
adipinic acid monoethyl ester
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611-10-9
2-ethoxycarbonyl-1-cyclopentanone
| Conditions | Yield |
|---|---|
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With
aluminium trichloride; triethylamine;
In
dichloromethane;
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71%
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at 270 - 280 ℃;
bei der thermischen Zersetzung;
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611-10-9 Upstream products
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64-17-5
ethanol
-
53007-35-5
1,1,4-butanetricarboxylic acid triethyl ester
-
141-52-6
sodium ethanolate
-
626-86-8
adipinic acid monoethyl ester
611-10-9 Downstream products
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