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Top Quality Chinese Factory supply 4353-77-9 TRIMETHYLSILYL CHLOROSULFONATE
- Molecular Formula: C3H9ClO3SSi
- Molecular Weight: 188.707
- Vapor Pressure: 2.09mmHg at 25°C
- Melting Point: -26 °C (lit.)
- Refractive Index: n20/D 1.424(lit.)
- Boiling Point: 169 °C at 760 mmHg
- Flash Point: 51 °C
- PSA： 51.75000
- Density: 1.236 g/cm3
- LogP: 2.40230
TRIMETHYLSILYL CHLOROSULFONATE(Cas 4353-77-9) Usage
|
General Description |
Trimethylsilyl chlorosulfonate is commonly employed as sulfonating agent. |
InChI:InChI=1/C3H9ClO3SSi/c1-9(2,3)7-8(4,5)6/h1-3H3
4353-77-9 Relevant articles
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Schmidt,Schmidbaur
, (1962)
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A Novel Synthesis of the Monobactam Antibiotic Carumonam
Manchand, Percy S.,Luk, Kin-Chun,Belica, Peter S.,Choudhry, Satish C.,Wei, Chung Chen,Soukup, Milan
, p. 5507 - 5512 (2007/10/02)
A novel synthesis of the monobactam 4, a...
Insertion of Sulfur Trioxide into the N-Si bond of Anilinotrimethylsilane. An Improved Method for the Preparation of Free Phenylamidosulfuric Acid
Kanetani, Fujio,Okada, Eiji,Negoro, Kenji
, p. 2517 - 2520 (2007/10/02)
The reaction between anilinotrimethylsil...
UBER PEROXOVERBINDUNGEN 17 DARSTELLUNG UND EIGENSCHAFTEN VON ALKYL- UND TRIMETHYLSILYLDERIVATEN VON PEROXOSCHWEFELSAEUREN
Blaschette, Armand,Safari, Hassan
, p. 57 - 66 (2007/10/02)
The novel peroxides Me3SiOSO2OOR (3; R =...
REACTION OF BIS(TRIMETHYLSILYL) SULFATE WITH HYDROGEN HALIDES AND WITH PHOSPHORUS AND SULFUR HALIDES AND OXYHALIDES
Voronkov, M. G.,Roman, V. K.,Maletina, E. A.,Korotaeva, I. M.
, p. 621 - 623 (2007/10/02)
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4353-77-9 Process route
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-
75-77-4
chloro-trimethyl-silane
-
-
4353-77-9
chlorosulfonate de trimethylsilyle
| Conditions | Yield |
|---|---|
|
With
sulfur trioxide;
at 50 ℃;
for 0.166667h;
|
87%
|
|
With
sulfur trioxide;
|
|
|
With
chlorosulphuric acid;
|
|
|
With
sulfur trioxide;
Ambient temperature;
|
91.5 g
|
-
-
18306-29-1
bis(trimethylsilyl)sulphate
-
-
75-77-4
chloro-trimethyl-silane
-
-
4353-77-9
chlorosulfonate de trimethylsilyle
| Conditions | Yield |
|---|---|
|
With
thionyl chloride;
at 120 ℃;
|
97%
92% |
|
With
thionyl chloride;
at 70 - 120 ℃;
Yields of byproduct given;
|
97%
|
|
With
thionyl chloride;
at 80 - 120 ℃;
|
97%
|
|
With
thionyl chloride;
at 120 ℃;
|
97%
|
4353-77-9 Upstream products
-
75-77-4
chloro-trimethyl-silane
-
18306-29-1
bis(trimethylsilyl)sulphate
-
29938-10-1
Bis(trimethylsilyl)peroxodisulfat
-
7446-11-9
sulfur trioxide
4353-77-9 Downstream products
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10090-05-8
trimethylsilyl methanesulfonate
-
10090-11-6
1,4-Bis-
-benzoldisulfonat -
1899-77-0
4-Trimethylsilyl-benzolsulfonsaeure-trimethylsilylester
-
62399-01-3
1,1,3,3-tetramethyl-1,3-dicyclohexyldisiloxane
